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Pokolbin is a rural locality in the Hunter Region of New South Wales Australia. It is part of the Singleton Council local government area and the city of Cessnock. The area is the centre of the Lower Hunter Valley wine region. Pokolbin lies within the Hunter Valley Important Bird Area. Pokolbin is surrounded by the Pokolbin subregion of the Hunter wine region, which includes numerous wineries, ranging from large multi- national to small family run operations, many of which are popular tourist destinations. Pokolbin is about 122 kms north of NSW's capital city of Sydney. In the 2011 Australian census the population of Pokolbin was 694 when there were 331 Females and 363 Males living there. The median age for people living in Pokolbin was 44.